This section is from the book "Facts Worth Knowing", by Robert Kemp Philip. Also available from Amazon: Inquire Within for Anything You Want to Know.
So many serious fires have been caused by chimneys catching fire, and not being quickly extinguished, that the following method of doing this should be made generally known. - Throw some powdered brimstone on the fire in the grate, or ignite some on the hob, and then put a board or something in the front of the fire-place, to prevent the fumes descending into the room. The vapour of the brimstone ascending the chimney, will then effectually extinguish the soot on fire. (See 28.)
 
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